Statistical mechanical theory for nonequilibrium systems. X. Nonequilibrium phase transitions.

نویسنده

  • Phil Attard
چکیده

A general theory for the stability and coexistence of nonequilibrium phases is formulated. An integral formulation of the second entropy is given, the functional maximization of which yields nonlinear hydrodynamics. Rayleigh-Bénard convection is analyzed, and analytic approximations are obtained for the second entropy for conduction and for convection. Despite the simplicity of the model, coexistence is predicted for a Rayleigh number within 5% of the known value.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 131 18  شماره 

صفحات  -

تاریخ انتشار 2009